Reactivity of aminocarbene complexes of chromium containing a coordinated CC double bond towards alkynes: Formation of azabicyclo[4.1.0]heptene systems
| Autor: | Henri Rudler, R. Yefsah, Andrée Parlier, Cecilio Alvarez |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
chemistry.chemical_classification
Denticity Double bond Cyclopropanation Ligand Organic Chemistry Biochemistry Medicinal chemistry Heptene Inorganic Chemistry chemistry.chemical_compound chemistry Intramolecular force Materials Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Carbene |
| Zdroj: | Journal of Organometallic Chemistry. 328:C21-C24 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(87)80258-9 |
| Popis: | Chromium complexes containing the bidentate aminocarbene-alkene ligand react with alkynes to give, after insertion followed by an intramolecular cyclopropanation reaction, azabicyclo[4.1.0]heptene systems, which react rapidly with oxygen, during work up, to lead to the corresponding cyclopropanic amidoketones. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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