The role of the nature and the purity of the alumina support on the hydrodesulfurization activity of CoMo sulfides

Autor:	Francis Luck, Marc J. Ledoux, Edd Blekkan, André Peter
Rok vydání:	1995
Předmět:	Pore diameter Chemistry Impurity Process Chemistry and Technology Inorganic chemistry Selectivity Hydrodesulfurization Catalysis Amorphous solid
Zdroj:	Applied Catalysis A: General. 133:321-333
ISSN:	0926-860X
Popis:	Pure γ-alumina as support for CoMo sulfided catalysts is compared in terms of physical and catalytic hydrodesulfurization (HDS) properties to other supports. γ-alumina containing foreign elements as impurities, i.e. Mg, Ca, Na, Fe, Cl, S and P does not exhibit significant changes. Other crystalline phases such as η, θ, χ or amorphous aluminas as support show important decreases in HDS activity of the corresponding CoMo catalysts. This activity is linearly correlated to the mean pore diameter of the support. Other supports such as TiO 2 , ZrO 2 , MgO, CeO 2 and SiO 2 not only show lower activities but also changes in selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3853be23161f2dabede8b13156fdbb18 https://doi.org/10.1016/0926-860x(95)00179-4 Zobrazit plný text záznamu Full Text from ScienceDirect