Organocobalt cluster complexes IX. A new general route to alkylidynetricobalt nonacarbonyl complexes
| Autor: | John E. Hallgren, Paul L.K. Hung, Dietmar Seyferth |
|---|---|
| Rok vydání: | 1972 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Aryl Organic Chemistry Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Materials Chemistry Trifluoroacetic acid Cluster (physics) Physical and Theoretical Chemistry Triethylsilane Tetrahydrofuran Alkyl |
| Zdroj: | Journal of Organometallic Chemistry. 44:C55-C58 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)82902-2 |
| Popis: | Alkylidynetricobalt nonacarbonyl complexes, RCH 2 CCo 3 (CO) 9 , where R is alkyl or aryl, were prepared in high yield by the reduction of the appropriate ketones, RC(O)CCo 3 (CO) 9 , with triethylsilane/trifluoroacetic acid in refluxing tetrahydrofuran. |
| Databáze: | OpenAIRE |
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