Vinylboranes as trans-dihydroxyethylene equivalents for diels-alder reactions

Autor:	Anikó M. Redman, Daniel A. Singleton
Rok vydání:	1994
Předmět:	chemistry.chemical_compound Ethylene Chemistry Yield (chemistry) Organic Chemistry Drug Discovery Diels alder Organic chemistry Stereoselectivity Biochemistry
Zdroj:	Tetrahedron Letters. 35:509-512
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)75824-2
Popis:	Several vinylboranes were explored as trans -1,2-dihydroxyethylene equivalents for Diels-Alder reactions. Use of the 1,2-bis(boryl)ethylene 4 allows the direct formation of 1,2-dihydroxycyclohexenes in high yield. The 2-phenyldimethylsilylvinylborane 8 is a good alternative that allows for hydroxyl-group differentiation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::382a5621360496bbef1111b28ee98ec4 https://doi.org/10.1016/s0040-4039(00)75824-2 Zobrazit plný text záznamu