Addition reactions of 1,1,1-trifluoro-4-trimethylstannylbut-3-yn-2-one and 1,1,1-trifluorobut-3-yn-2-one to some tetrahydropyridines. Synthesis of trifluoroacylated polysubstituted tetrahydroazocines
Autor: | Valery N. Kalinin, A. B. Koldobskii, E. V. Solodova |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 59:1010-1013 |
ISSN: | 1573-9171 1066-5285 |
DOI: | 10.1007/s11172-010-0197-x |
Popis: | A reaction of tetrahydropyridines, obtained by the Diels-Alder reaction from α,β-unsat-urated N,N-dimethylhydrazones and methyl acrylate, with acetylenes activated with the trifluoroacetyl group has been studied and found to lead to polysubstituted trifluoroacylated tetrahydroazocines. No cyclobutene intermediates have been detected. |
Databáze: | OpenAIRE |
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