Addition reactions of 1,1,1-trifluoro-4-trimethylstannylbut-3-yn-2-one and 1,1,1-trifluorobut-3-yn-2-one to some tetrahydropyridines. Synthesis of trifluoroacylated polysubstituted tetrahydroazocines

Autor: Valery N. Kalinin, A. B. Koldobskii, E. V. Solodova
Rok vydání: 2010
Předmět:
Zdroj: Russian Chemical Bulletin. 59:1010-1013
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-010-0197-x
Popis: A reaction of tetrahydropyridines, obtained by the Diels-Alder reaction from α,β-unsat-urated N,N-dimethylhydrazones and methyl acrylate, with acetylenes activated with the trifluoroacetyl group has been studied and found to lead to polysubstituted trifluoroacylated tetrahydroazocines. No cyclobutene intermediates have been detected.
Databáze: OpenAIRE