On the structure and conformational composition of 1,1-bis(methylthio)ethylene

Autor:	T. Torgrimsen, Hans Martin Seip, P. Jandal
Rok vydání:	1976
Předmět:	Ethylene Organic Chemistry Analytical Chemistry Inorganic Chemistry Bond length chemistry.chemical_compound Crystallography symbols.namesake chemistry Electron diffraction Phase (matter) symbols Composition (visual arts) Raman spectroscopy Conformational isomerism Spectroscopy
Zdroj:	Journal of Molecular Structure. 32:369-377
ISSN:	0022-2860
DOI:	10.1016/0022-2860(76)85014-4
Popis:	1,1-bis(methylthio)ethylene has been studied in the gaseous phase by electron diffraction and in the solid and liquid phases by Raman spectroscopy. While there is apparently only one conformer in the solid, the fluid phases consist of probably three forms, two of these have a non-planar skeleton. Average values for the bond lengths are: r a (C eth —S) = 1.767 A, r a (C met —S) = 1.815 A, r a (CC) = 1.348 A.
Databáze:	OpenAIRE
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