Synthesis and Study of the First N-Aryl Acyclic Diaminocarbene and Its Transition-Metal Complexes

Autor:	and Shanmuganathan Saravanakumar, Matthew D. Sanderson, Christopher W. Bielawski, Evelyn L. Rosen
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_compound Transition metal Stereochemistry Chemistry Ligand Aryl Organic Chemistry Substitution (logic) Physical and Theoretical Chemistry
Zdroj:	Organometallics. 26:5774-5777
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om7007925
Popis:	The first acyclic diaminocarbene (ADC) featuring N-aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5-cis,cis-cyclooctadiene) and (ADC)RhCl(CO)2, were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N-aryl groups through judicious N substitution was also explored.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::38128122d3fbff70b4f1b7f4c2b540b8 https://doi.org/10.1021/om7007925 Zobrazit plný text záznamu