New nitrogenated siloxy butadienes from 1,3-dichloroacetone

Autor:	Manuel Medarde, Dulce Alonso, Fernando Tomé, Esther Caballero
Rok vydání:	2007
Předmět:	chemistry.chemical_compound chemistry Silylation Organic Chemistry Drug Discovery Substitution (logic) Wittig reaction Organic chemistry Biochemistry Phosphorane
Zdroj:	Tetrahedron Letters. 48:907-910
ISSN:	0040-4039
Popis:	New 1-formamido-2-siloxy-1,3-butadienes have been generated from 1,3-dichloroacetone by means of phosphorane formation, formamido substitution, Wittig olefination and silylation. The procedure demonstrates the utility and versatility of this methodology for the formation of polysubstituted dienes, designed as useful building blocks for the synthesis of polycyclic alkaloids and related analogues.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3808d6aa445291a0c14d2db4c92fc16f https://doi.org/10.1016/j.tetlet.2006.12.039 Zobrazit plný text záznamu Full Text from ScienceDirect