Phase relations in the systems A2TeI6-Tl2TeI6 (A = K, Rb, Cs) and A2TeBr6-A2TeI6 (A = K, Rb, Cs, Tl(I))

Autor:	E. Yu. Peresh, O. V. Zubaka, V. I. Sidei
Rok vydání:	2005
Předmět:	Inorganic Chemistry Ionic radius Chemistry Stereochemistry General Chemical Engineering Phase (matter) Materials Chemistry Metals and Alloys Analytical chemistry Phase relation Structure type Solid solution Eutectic system
Zdroj:	Inorganic Materials. 41:298-302
ISSN:	1608-3172 0020-1685
DOI:	10.1007/s10789-005-0127-8
Popis:	Phase relations in the systems K2TeI6-Tl2TeI6 (I), Rb2TeI6-Tl2TeI6 (II), Cs2TeI6-Tl2TeI6 (III), K2TeBr6-K2TeI6 (IV), Rb2TeBr6-Rb2TeI6 (V), Cs2TeBr6-Cs2TeI6 (VI), and Tl2TeBr6-Tl2TeI6 (VII) are studied. System VI contains a continuous series of solid solutions, while the other systems have eutectic phase relations with rather broad solid-solution ranges. The relationship between the ionic radii of A+ and Hal- (Hal = Br, I) is shown to play a key role in determining the structure type of the A2TeHal6 compounds and the phase relations in the systems studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::37ec84f27f2e6b49f1246f53ec86e5ea https://doi.org/10.1007/s10789-005-0127-8 Zobrazit plný text záznamu Plný text ve formátu PDF