ChemInform Abstract: Radical Products of the Oxidation of 2,2-Diacyl-1-arylhydrazines with the System Pb(OAc)4-CF3COOH-CH2Cl2

Autor: Ralph Kluge, L. Omelka, Manfred Schulz
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 26
ISSN: 0931-7597
DOI: 10.1002/chin.199528061
Popis: The oxidation of 2,2-Diacyl-1-arylhydrazines1a–l with the system Pb(OAc)4-CF3COOH-CH2Cl2 led to the formation of two types of radical products. Phenazinium cation radicals5a–h were formed from 2,2-diacyl-1-arylhydrazines1a–h, while hydrazyl radicals2i–l were observed to be the only radical products of the oxidation of1i–l. The generated radicals are characterized by their EPR parameters.
Databáze: OpenAIRE