Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands

Autor: Vasily V. Bashilov, Fedor M. Dolgushin, Kim P. Butin, Tatiana V. Magdesieva, D. N. Kravchuk, V. I. Sokolov
Rok vydání: 2004
Předmět:
Zdroj: Russian Chemical Bulletin. 53:795-799
ISSN: 1066-5285
DOI: 10.1023/b:rucb.0000037844.93864.3c
Popis: Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum-chemical calculations. Probable sites of localization of electronic changes in the molecules of these complexes under electrochemical oxidation and reduction were determined.
Databáze: OpenAIRE