Annulation of aryl rings and formation of pyrones involving depalladation of organometallic compounds

Autor: Guy Le Borgne, Jean Fisher, Michell Pfeffer, André De Cian, Marc A. Rotteveel
Rok vydání: 1991
Předmět:
Zdroj: Journal of Organometallic Chemistry. 413:C15-C19
ISSN: 0022-328X
DOI: 10.1016/0022-328x(91)80073-s
Popis: The depalladation of various organopalladium compounds, derived from cyclopalladated complexes in which two alkynes have been inserted into their Pd–C bonds, affords organic products containing six-membered rings. The latter are obtained either by de-alkylation of an ester group or by annulation of an aryl ring, the ester and the aryl units being substituents on the alkynes used in the synthesis of the starting materials.
Databáze: OpenAIRE