The molecular Zeeman effect in vinyl formate using a conventional Stark modulated spectrometer and a Fourier transform spectrometer

Autor:	D. Krajnovich, H. L. Voss, W. E. Hoke, W. H. Flygare
Rok vydání:	1978
Předmět:	Zeeman effect Spectrometer Fourier transform spectrometers Analytical chemistry General Physics and Astronomy Magnetic susceptibility chemistry.chemical_compound symbols.namesake chemistry Quadrupole symbols Formate Physical and Theoretical Chemistry Atomic physics Anisotropy
Zdroj:	The Journal of Chemical Physics. 68:1439-1443
ISSN:	1089-7690 0021-9606
Popis:	The rotational Zeeman effect in vinyl formate was observed. The rotational molecular g values are gaa=−0.1759±0.0010, gbb=−0.0342±0.0006, and gcc=−0.0059±0.0006. The magnetic susceptibility anisotropies in units of 10−6 erg G−2 mole−1 are 2χaa−χbb−χcc=9.5±1.3 and 2χbb−χaa−χcc=20.8±1.1. The molecular quadrupole moments in units of 10−26 esu cm2 are Qaa=−0.1±1.4, Qbb=+1.2±1.4, and Qcc=−1.1±2.2. The relative performance of Stark modulated and Fourier transform spectrometers is examined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::37b5f0a9f0cf9e5a5f14608b640b2b07 https://doi.org/10.1063/1.435965 Zobrazit plný text záznamu