A framework ensemble facilitates high Pt utilization in a low Pt loading fuel cell

Autor:	Jian Wang, Qiang Liao, Zidong Wei, Wenhui Xuan, Yong Feng, Guangping Wu, Wei Ding, Lishan Peng, Li Li
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Materials science chemistry Chemical engineering Continuous operation Nafion Mass transfer Membrane electrode assembly Proton exchange membrane fuel cell Nanoparticle Energy technology Catalysis
Zdroj:	Catalysis Science & Technology. 11:2957-2963
ISSN:	2044-4761 2044-4753
Popis:	Proton-exchange membrane fuel cells (PEMFCs) are a clean, zero-emission, and promising energy technology for future use. The scale-up of PEMFCs drives up the cost of Pt resources, a key catalytic material for fuel cells; this inevitably necessitates the development of low-Pt-usage and high-Pt-utilization technology for PEMFCs. Herein, we report a low-Pt-loading membrane electrode assembly (MEA) featuring a three-dimensional (3D) carbon framework with embedded PtZn intermetallic nanoparticles (iNPs) and vacuum-aspirated Nafion ionomers. Such a framework ensemble shows efficient mass transfer for various species (protons, O2, and water) to the PtZn iNPs. As a result, the maximum power output reaches 826 mW cm−2 at a loading of 60 μgPt cm−2 for a PEMFC fabricated with the as-prepared MEA, and a high Pt utilization of 145 mgPt kW−1 is realized, which is 1.6 times greater than that of a commercial Pt/C catalyst. Moreover, excellent stability is achieved at low Pt loading (60 μgPt cm−2), with no decay occurring during 300 h of continuous operation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::37a5d374a790f191399cfc135e5d82e0 https://doi.org/10.1039/d1cy00028d Zobrazit plný text záznamu