Transformation of white phosphorus in the coordination sphere of nickel complexes with σ-donating ligands
Autor: | Vladimir I. Morozov, A. G. Kafiyatullina, Roman Kuznetsov, Oleg G. Sinyashin, Yu. H. Budnikova, Anna S. Balueva |
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Rok vydání: | 2003 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 52:2419-2423 |
ISSN: | 1066-5285 |
Popis: | Oxidation of white phosphorus in the coordination sphere of the nickel(ii) complex with 1,1,1-tris(diphenylphosphinomethyl)ethane and 1,1",5,5"-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) was shown to be possible and accompanied by the transformation of P4 into the σ-P3 ligand. The change in the nickel state was monitored by cyclic voltammetry, 31P NMR spectroscopy, ESR, and IR spectroscopy. |
Databáze: | OpenAIRE |
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