Facile Synthesis of Spherical Polyelectrolyte Brushes as Carriers for Conducting Polymers to be Used in Plastic Electronics
| Autor: | Gerhard Wegner, François Rime, Hans-Juergen Butt, Elmar Bonaccurso, Andreas Muehlebach, Konstantinos Mpoukouvalas, Gunther Brunklaus, Birgit Fassbender, Ling Sun, Jianjun Wang |
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| Rok vydání: | 2009 |
| Předmět: |
Conductive polymer
Materials science Polymers and Plastics Organic Chemistry Nanoparticle Condensed Matter Physics Polypyrrole Polymer brush Polyelectrolyte Styrene Dielectric spectroscopy chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Copolymer Physical and Theoretical Chemistry |
| Zdroj: | Macromolecular Chemistry and Physics. 210:1504-1509 |
| ISSN: | 1521-3935 1022-1352 |
| DOI: | 10.1002/macp.200900199 |
| Popis: | A two-step method for the preparation of spherical polyelectrolyte brushes (SPBs) has been developed. Copolymerization of styrene and divinyl benzene at the particle surface resulted in a large number of accessible vinyl groups. These vinyl groups reacted with sodium styrene sulfonate to give SPBs. The SPBs were used as carriers for conducting polymers resulting in redispersible conducting inks with good film forming properties. Direct current (DC) conductivity of the polypyrrole (PPy) loaded samples showed a percolating behavior as probed by impedance spectroscopy. Finally, device performance of organic light-emitting diodes based on the conducting thin films assembled from the PPy loaded particles was tested. |
| Databáze: | OpenAIRE |
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