Determination of a fraction of spin-correlated radical ion pairs in irradiated alkanes by quantum oscillation technique

Autor:	B.M. Tadjikov, Yu. N. Molin, V.M. Grigoryants, O. M. Usov
Rok vydání:	1997
Předmět:	Viscosity Radiation Amplitude Radical ion Condensed matter physics Chemistry Analytical chemistry Electron beam processing Quantum oscillations Irradiation Singlet state Spin-½
Zdroj:	Radiation Physics and Chemistry. 49:237-243
ISSN:	0969-806X
DOI:	10.1016/s0969-806x(96)00141-7
Popis:	Amplitudes of quantum oscillations observed in the recombination fluorescence of the (diphenylsulfide-d10)+/(p-terphenyll-d14)− radical ion pairs in alkanene solutions have been used to estimate a fraction of spin-correlated singlet pairs Θ in the radiation track. Θ values of 0.36 – 0.54 for the solvent series studied were found. Values for a fraction of singlet recombinations fs (0.52–0.66), calculated from Θ values, are in satisfactory agreement with those available from literature. It has been observed that Θ and fs values decrease with increasing solvent viscosity (from n-hexane to cis-decalin).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3771d4d98d4ea8faf3bc2d5c9f8c6dbb https://doi.org/10.1016/s0969-806x(96)00141-7 Zobrazit plný text záznamu Full Text from ScienceDirect