ChemInform Abstract: Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide-Functionalized NHC Ligand

Autor:	Satoshi Sakaguchi, Hiromu Tokura, Shun Kawabata, Masaki Okamoto, Hiroyuki Chiyojima
Rok vydání:	2012
Předmět:	chemistry.chemical_compound chemistry Ligand chemistry.chemical_element Stereoselectivity General Medicine Iridium Carbene Combinatorial chemistry Acetophenone Catalysis
Zdroj:	ChemInform. 43
ISSN:	0931-7597
DOI:	10.1002/chin.201233024
Popis:	The air- and moisture-stable isoleucinol-derived iridium carbene complex IRI in combination with AgBF4 efficiently catalyzes the stereoselective reduction of a variety of acetophenone derivatives and analogues at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::37325215951be388672dad8df93139af https://doi.org/10.1002/chin.201233024 Zobrazit plný text záznamu Plný text