Investigations on organotin compounds. XXI: The preparation of organotin-substituted acetylenes by the decarboxylation of organotin acetylenecarboxylates

Autor:	G.J.M. van der Kerk, J. G. A. Luijten
Rok vydání:	2010
Předmět:	Diethyl acetylenedicarboxylate chemistry.chemical_compound chemistry Decarboxylation Tributyltin azide Carbon dioxide Organic chemistry Disproportionation General Chemistry
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 83:295-300
ISSN:	0165-0513
DOI:	10.1002/recl.19640830310
Popis:	A number of triorganotin salts of acetylenemono- and di-carboxylic acids upon being heated lose carbon dioxide to give organotin-substituted acetylenes. Some others decompose in an irregular way and in one case simultaneous decarboxylation and disproportionation occurs. Tributyltin azide adds to diethyl acetylenedicarboxylate with the formation of 1-tributylstannyl-4,5-di-ethoxycarbonyl-1,2,3-triazole.
Databáze:	OpenAIRE
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