Organodimagnesium derivatives of thiophene

Autor:	Yu. P. Dormidontov, I. I. Lapkin, Yu. V. Shklyaev
Rok vydání:	1982
Předmět:	Steric effects chemistry.chemical_compound Chemistry Organic Chemistry Thiophene Ether Medicinal chemistry Diethyl oxalate
Zdroj:	Chemistry of Heterocyclic Compounds. 18:569-572
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00506143
Popis:	It was established that 2,5-dibromo-3-R-4-arylthiophenes form organodimagnesium compounds in ether with the “accompaniment” of dibromoethane. It is shown that because of steric hindrance, only 2-ethoxalyl-3-R-4-arylthiophenes are formed in the reaction of the organodimagnesium compounds with diethyl oxalate. It was established that the bromomagnesiumethoxycarbinolates obtained from the indicated thiophenes and bromomagnesium ethoxide have high thermal stabilities. The IR and PMR Spectra of the synthesized compounds were studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::370a67ef5abddb836e9d417e980cd552 https://doi.org/10.1007/bf00506143 Zobrazit plný text záznamu Full text from SpringerLink