Synthesis, Characterization, and Photocatalytic Properties of Bismuth (III)-benzene-1,3,5-tricarboxylate
| Autor: | Jiang-Feng Song, Xu-Hong Wu, Zhi-Xian Wei, Fan Ye, Pan Yue |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Tricarboxylate 0104 chemical sciences Coordination complex Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Ultraviolet light Photocatalysis Methyl orange Thermal stability 0210 nano-technology |
| Zdroj: | Zeitschrift für anorganische und allgemeine Chemie. 643:669-674 |
| ISSN: | 0044-2313 |
| Popis: | {[Bi(BTC)(H2O)2]·H2O}n (H3BTC = 1,3,5-benzenetricarboxylic acid) was synthesized by an eco-friendly hydrothermal method and characterized by single-crystal X-ray diffraction, IR and UV/Vis spectroscopy, photoluminescence (PL), and thermogravimetric analyses. The complex featured a 3D metal-organic framework with Bi2 secondary building units. In the complex, the central Bi3+ is nine-coordinate, three central Bi atoms and three BTC3– anions are interconnected into a ring with the dimension of 7.95 × 9.89 A2. Moreover, the complex is decomposed at over 388 °C, showing its highly thermal stability. Further, the complex exhibits photocatalytic activity for the degradation of methyl orange (MO) solution under UV light irradiation, and its structure can keep consistent with the original one after 9 h photocatalytic reaction, indicating that it is also very stable under UV light. Therefore, it could be anticipated the novel coordination complex will be a stable ultraviolet light catalyst. |
| Databáze: | OpenAIRE |
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