Enclathration of Picoline Isomers by (rac)-TADDOLs: Structures, Selectivity, and Thermal Analysis
| Autor: | Emma J. Tiffin, Nicole M. Sykes, Neil Ravenscroft, Luigi R. Nassimbeni, Edwin Weber |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry General Chemistry Crystal structure 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Inclusion compound chemistry.chemical_compound Crystallography Differential scanning calorimetry General Materials Science Picoline Thermal stability Selectivity Thermal analysis |
| Zdroj: | Crystal Growth & Design. 19:1880-1887 |
| ISSN: | 1528-7505 1528-7483 |
| Popis: | In this investigation, we studied the preferences of three α,α,α′,α′-tetraphenyl-l,3-dioxolane-4,5-dimethanol (TADDOL)-derived host compounds toward the isomers of methyl-pyridines (picolines). Ten novel inclusion compounds were synthesized, and their structural and thermal properties were further characterized. Binary competition experiments were performed, and all three hosts discriminate between the picoline isomer guests. Interestingly, all three hosts display different preferences toward the isomers, and these results were rationalized by their resulting crystal structures and packing analysis and correlated to their differential scanning calorimetry (DSC) results. DSC results showed a correlation between the thermal stability of an inclusion compound and the preference of the host toward a given isomer. |
| Databáze: | OpenAIRE |
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