Spectral, Magnetic and Electrical Studies on Complexes of some First Row Transition Elements with 2,9-Dimethyl-4,7-Diphenyl-1,10-Phenanthroline
| Autor: | J.R. Allan, A. D. Paton, K. Turvey, D.L. Gerrard, H.J. Bowley |
|---|---|
| Rok vydání: | 1989 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Chemistry Inorganic chemistry chemistry.chemical_element Zinc Copper Metal Crystallography Nickel Octahedron Transition metal visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Cobalt Inorganic compound |
| Zdroj: | Journal of Coordination Chemistry. 19:303-310 |
| ISSN: | 1029-0389 0095-8972 |
| DOI: | 10.1080/00958978909408833 |
| Popis: | Some new compounds of 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline with cobalt(II), nickel(II), copper(II) and zinc(II), have been prepared in ethanolic solution. The cobalt, nickel and zinc compounds have tetrahedral structures while the copper compound has an octahedral structure. All of the compounds, including 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroIine itself, exhibit a superlinear I versus V relationship. It is concluded that the metal ion in the complexes does not play an important role in electrical conduction. |
| Databáze: | OpenAIRE |
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