[2-(3,5-Dibromo-2-oxidobenzylamino)-3-phenylpropanoato-κ3N,O,O′](1,10-phenanthroline-κ2N,N′)zinc(II) dihydrate

Autor: Shu-Hua Zhang, Li-Xia Jing, Xiao-Zhen Feng, Guang-Zhao Li, Zheng Liu
Rok vydání: 2007
Předmět:
Zdroj: Acta Crystallographica Section E Structure Reports Online. 63:m396-m398
ISSN: 1600-5368
Popis: In the title complex, [Zn(C16H13Br2NO3)(C12H8N2)]·2H2O or [Zn(L)(phen)]·2H2O, [LH2 = 2-(3,5-dibromo-2-hydr­oxy-benzyl­amino)-3-phenylpropionic acid and phen = 1,10-phenanthroline], the ZnII atom is coordinated in a slightly distorted square-pyramidal geometry by two O atoms and one N atom from an L2− ligand and two N atoms from a phen ligand. One of the carboxyl­ate O atoms is in the apical position. In the crystal structure, complex mol­ecules are linked into a chain along the c axis through N—H⋯O hydrogen bonds; the water mol­ecules are connected to the chains via O—H⋯O hydrogen bonds.
Databáze: OpenAIRE