Synthesis, structural characterization and electrochemical study of 1,1′-ferrocenylene labeled amino acids
| Autor: | Evdoxia Coutouli-Argyropoulou, Christos Sideris, George Kokkinidis |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Organic Chemistry Substituent Carbon-13 NMR Conjugated system Biochemistry Medicinal chemistry Amino acid Inorganic Chemistry chemistry.chemical_compound chemistry Ferrocene Materials Chemistry Proton NMR Moiety Organic chemistry Physical and Theoretical Chemistry Cyclic voltammetry |
| Zdroj: | Journal of Organometallic Chemistry. 691:3909-3918 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2006.05.045 |
| Popis: | Unsymmetrical 1,1′-disubstituted ferrocenes bearing an amino acid moiety and a conjugated electron density controlling substituent were synthesized conveniently starting from 1,1′-ferrocenedicarbaldehyde. The novel ferrocene amino acid derivatives were completely characterized from their MS, 1 H NMR and 13 C NMR spectra. Their electrochemical behavior was studied by cyclic voltammetry. Their formal redox potentials E f were slightly influenced by the nature of the amino acid and mainly by the kind of the ethenyl substituent. Furthermore all the ( Z )-isomers exhibited a slight anodic shift compared with the corresponding ( E )-isomers. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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