Mechanism of the partial oxidation of methane to synthesis gas on a silica-supported nickel catalyst

Autor:	E.R. Stobbe, J.W. Geus, F. van Looij, J.C. van Giezen
Rok vydání:	1994
Předmět:	chemistry.chemical_compound chemistry Carbon dioxide reforming Membrane reactor Methane reformer Methanizer Inorganic chemistry Water gas Oxidative coupling of methane General Chemistry Catalysis Methane Syngas
Zdroj:	Catalysis Today. 21:495-503
ISSN:	0920-5861
DOI:	10.1016/0920-5861(94)80172-x
Popis:	In the present study we investigated the mechanism involved in the partial oxidation of methane with oxygen to synthesis gas on a reduced silica-supported nickel catalyst in an isothermal fixed-bed reactor at temperatures up to 920 K. Firstly, the deep oxidation of methane with oxygen to carbon dioxide and water proceeds. Subsequently, the remaining part of the methane reacts with the initially formed water and carbon dioxide to synthesis gas. The final hydrogen-to-carbon monoxide ratio is determined by the water-gas shift conversion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::36ae3d8acc3bb49a60f2b7e37fa5b6f5 https://doi.org/10.1016/0920-5861(94)80172-x Zobrazit plný text záznamu