Reactions of elemental phosphorus and phosphine with electrophiles in superbasic systems: XX. Phosphorylation of 4-vinylbenzyl chloride with elemental phosphorus

Autor:	Yu. V. Smetannikov, Boris G. Sukhov, Svetlana F. Malysheva, Vladimir A. Kuimov, Nina K. Gusarova, Boris A. Trofimov, Natalia Tarasova
Rok vydání:	2007
Předmět:	Phosphine oxide Aqueous solution White Phosphorus Phosphorus Inorganic chemistry chemistry.chemical_element General Chemistry Chloride Catalysis chemistry.chemical_compound chemistry Electrophile medicine Phosphine Nuclear chemistry medicine.drug
Zdroj:	Russian Journal of General Chemistry. 77:1880-1886
ISSN:	1608-3350 1070-3632
Popis:	4-Vinylbenzyl chloride reacts with white and red phosphorus, as well as with nanostructured “activated” red phosphorus (complex organophosphorus polymer prepared from white phosphorus under ionizing radiation) in the system concentrated aqueous KOH-dioxane-phase-transfer catalyst (20–50°C, argon) to form tris(4-vinylbenzyl)phosphine oxide, along with (4-vinylbenzyl)- and bis(4-vinylbenzyl)phosphinic acids, the yield and product ratio being dependent on both the reaction conditions and the nature of the phosphorylating agent. The nanostructured “activated” red phosphorus is more reactive than ordinary commercial red phosphorus.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::36a5d957377f9624c800211b72f2f0bf https://doi.org/10.1134/s1070363207110060 Zobrazit plný text záznamu Plný text ve formátu PDF