A novel metal–organic framework based on hexanuclear Co(ii ) clusters as an anode material for lithium-ion batteries
| Autor: | Wei-Qiu Kan, Jiaqin Yang, Yuan-Chun He, Yang Yu, Yao-Yao Fan, Zhi-Hong Jing, Yan Yang, Lingyan Wang, Jinmao You |
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| Rok vydání: | 2018 |
| Předmět: |
Battery (electricity)
Materials science Composite number chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Electrochemistry 01 natural sciences Magnetic susceptibility 0104 chemical sciences Anode chemistry Chemical engineering Cluster (physics) General Materials Science Metal-organic framework Lithium 0210 nano-technology |
| Zdroj: | CrystEngComm. 20:5576-5582 |
| ISSN: | 1466-8033 |
| DOI: | 10.1039/c8ce01039k |
| Popis: | A new metal–organic framework, [Co(L)]·1.5H2O (1), has been successfully synthesized from an organic ligand, 3-carboxy-1-(4′-carboxybenzyl)-2-oxidopyridinium. Compound 1 displays a novel 3D framework with a capsule-shaped cavity and a hexanuclear [Co6] cluster. The temperature-dependent magnetic susceptibility of compound 1 has been investigated. The electrochemical application of compound 1 as a lithium-ion battery anode material was also explored. To improve the electrochemical performance of compound 1, we utilized compound 1 as a novel precursor to prepare a Co3O4@C composite. By comparison, the Co3O4@C composite shows a higher capacity and better cycling performance, which provides a new direction for the design of anode materials for lithium-ion batteries. |
| Databáze: | OpenAIRE |
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