Intermolecular Highly Regioselective Hydroamination of Alkenes with Ligandless Platinum(II) Catalysts in Ionic Solvents: Activation Role of n-Bu4PBr

Autor:	Ngoc Chau Chu, Jean-Jacques Brunet, Ousmane Diallo
Rok vydání:	2005
Předmět:	Chemistry Organic Chemistry Markovnikov's rule Intermolecular force Ionic bonding Regioselectivity chemistry.chemical_element Catalysis Inorganic Chemistry chemistry.chemical_compound Aniline Organic chemistry Hydroamination Physical and Theoretical Chemistry Platinum
Zdroj:	Organometallics. 24:3104-3110
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om040142s
Popis:	The reaction of aniline with 1-hexene catalyzed by PtBr2 (0.3%) in the presence of n-Bu4PBr (65 equiv/Pt) at 150 °C affords the expected hydroamination products with a 95% Markovnikov regioselectiv...
Databáze:	OpenAIRE
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