Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- vs. exohedral geometry

Autor:	Kento Minamikawa, Shun Sarugaku, Masashi Arakawa, Akira Terasaki
Rok vydání:	2022
Předmět:	General Physics and Astronomy Physical and Theoretical Chemistry
Zdroj:	Physical Chemistry Chemical Physics. 24:1447-1455
ISSN:	1463-9084 1463-9076
DOI:	10.1039/d1cp04197e
Popis:	Cationic and anionic AgNM+/− (M = Sc–Ni) clusters are explored to examine the electron-counting rule. Among 18-valence-electron clusters, endohedrally doped ones are stable due to superatomic electron-shell closure involving delocalized 3d electrons.
Databáze:	OpenAIRE
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