Probing Molecular Cavities in α-Cyclodextrin Solutions by Xenon NMR

Autor:	Jacques Reisse, Stephen J. Heyes, Robert Ottinger, Kristin Bartik, Michel Luhmer
Rok vydání:	1995
Předmět:	chemistry.chemical_classification Cyclodextrin Chemical shift Intermolecular force General Engineering chemistry.chemical_element Nuclear Overhauser effect NMR spectra database Nuclear magnetic resonance Xenon chemistry Isotopes of xenon Physical chemistry Equilibrium constant
Zdroj:	Journal of Magnetic Resonance, Series B. 109:164-168
ISSN:	1064-1866
DOI:	10.1006/jmrb.1995.0005
Popis:	129 Xe NMR has been used to investigate intermolecular interactions between xenon and α-cyclodextrin in H 2 O and in DMSO. Nuclear Overhauser enhancement effects confirmed the formation of a xenon–cyclodextrin complex. Chemical shifts were measured in solutions containing different concentrations of α-cyclodextrin and in solutions containing linear oligosaccharides. The experimental data are interpreted on the basis of a three-site model for xenon. The binding characteristics of the xenon–cyclodextrin system, including the 129 Xe NMR chemical shift in the cavity and the equilibrium constants, were determined and are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::363b9bf2f2c1ca0a02a5d8e466e32d43 https://doi.org/10.1006/jmrb.1995.0005 Zobrazit plný text záznamu Full Text from ScienceDirect