Metallorganische lewis-säuren
| Autor: | Mathilde Appel, Wolfgang Beck |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
chemistry.chemical_classification
Tetrafluoroborate Stereochemistry Ligand Organic Chemistry Trimethylphosphine chemistry.chemical_element Fluorine-19 NMR Nuclear magnetic resonance spectroscopy Biochemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Fluorine Chemical solution Physical and Theoretical Chemistry Inorganic compound |
| Zdroj: | Journal of Organometallic Chemistry. 319:C1-C4 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(87)80356-x |
| Popis: | Zusammenfassung The coordination of the tetrafluoroborate ligand in Cp(OC)2(R3P)MoFBF3 (R = Me, Et) is confirmed by a 19F NMR study (at −80°C), the spectrum shows a double quartet for the metal-coordinated fluorine atom and a doublet for the terminal fluorine atoms. The 19F NMR spectrum of Cp(OC)2(Me3P)MoFBF3 shows equivalent fluorine atoms at room temperature. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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