Degradation of Selected PAHs in Soil/Compost and Identification of Intermediates
| Autor: | H Wischmann, G Montresori, Hans Steinhart, K Hupe, Rainer Stegmann |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Chromatography Compost Silica gel Health Toxicology and Mutagenesis Public Health Environmental and Occupational Health Soil Science Phenanthrene engineering.material Pollution High-performance liquid chromatography Analytical Chemistry Fluorone chemistry.chemical_compound Hydrocarbon chemistry Environmental chemistry engineering Environmental Chemistry Solid phase extraction Gas chromatography Waste Management and Disposal Water Science and Technology |
| Zdroj: | International Journal of Environmental Analytical Chemistry. 64:247-255 |
| ISSN: | 1029-0397 0306-7319 |
| DOI: | 10.1080/03067319608028346 |
| Popis: | Solvent-extractable degradation products of polycyclic aromatic hydrocarbons formed in a soil/compost mixture were analysed using a clean-up procedure including solid phase extraction. From glass columns, containing silica gel deactivated with 6% water, two fractions were eluted: a moderately polar fraction of ketones and quinones and a more polar fraction of phenolic compounds and organic acids. Such oxidation products were identified using reversed-phase high performance liquid chromatography and gas chromatography-mass spectrometrv. Applying this method to a degradation study on four selected PAHs in soil/compost mixtures. 1-hydroxy-2-naphthoic acid could be found in the system fortified with phenanthrene. and 9-fluorenol and 9-fluorenone were identified as degradation products of fluorone. The occurrence of the latter in sterilized controls show, that PAH metabolism is accompanied by abiotic degradation mechanisms. |
| Databáze: | OpenAIRE |
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