A study of the ion [Ta2OF10]2−
| Autor: | J. Sala-Pala, Anthony J. Edwards, J. C. Dewan, Jean-Yves Calves, Jacques E. Guerchais, S. Brownstein |
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| Rok vydání: | 1978 |
| Předmět: | |
| Zdroj: | Canadian Journal of Chemistry. 56:1545-1548 |
| ISSN: | 1480-3291 0008-4042 |
| DOI: | 10.1139/v78-250 |
| Popis: | Hydrolysis of (Et4N)[TaF6] with Et4NOH in organic medium gives (Et4N)2[Ta2OF10]. The Ta—O—Ta infrared and Raman frequencies reflect the linearity of the bridge, in agreement with a previous X-ray study. The 19F nmr spectrum is of the type AA′E4E4′. Chemical shifts are compared with other pseudo-octahedral species of tantalum with formula [TaF5L]. |
| Databáze: | OpenAIRE |
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