Voltammetric studies of metal chlorides in AlCl3–CsCl and ZnCl2–CsCl melts using an oscillating solid microelectrode

Autor:	S. N. Flengas, N. Kh. Tumanova, H. S. Ray
Rok vydání:	1977
Předmět:	Chemistry Organic Chemistry Inorganic chemistry Analytical chemistry General Chemistry Redox Catalysis Ion Metal Microelectrode TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY visual_art visual_art.visual_art_medium Qualitative inorganic analysis
Zdroj:	Canadian Journal of Chemistry. 55:656-668
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v77-094
Popis:	The oscillating planar solid microelectrode developed previously (1) has been used to investigate the reduction of the ions Co2+, Ni2+, Pb2+, Cd2+, Cu+, Ag+, as well as of the redox system Fe2+/Fe3+ in solvent melts containing various amounts of CsCl and AlCl3.Similarly, the reductions of the ions Co2+, Ni2+, and Cd2+ as well as Zr4+ have been investigated in solvent melts containing various amounts of CsCl and ZnCl2.Well-defined limiting currents have been obtained in all systems. These were found to vary linearly with the concentration of the solute. From the slopes of Evs. log (iL − i), or log i/(iL − i), the electrode reactions were established in most cases. The analysis of the results for Zr4+ indicates a three step reduction process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3619ecc896c1c345fd1ad44cb64c4ba9 https://doi.org/10.1139/v77-094 Zobrazit plný text záznamu