The X-ray structure and spectroscopy of platinum(II) complexes with 1,2,4-triazolo[1,5-a]pyrimidines and dimethylsulfoxide

Autor:	Tadeusz Głowiak, Iwona Łakomska, Jerzy Sitkowski, Leszek Pazderski, Edward Szłyk, Andrzej Surdykowski, Lech Kozerski
Rok vydání:	2002
Předmět:	Pyrimidine Chemistry Stereochemistry X-ray chemistry.chemical_element Crystal structure Chloride Medicinal chemistry Ion Inorganic Chemistry chemistry.chemical_compound Materials Chemistry medicine Molecule Physical and Theoretical Chemistry Platinum Spectroscopy medicine.drug
Zdroj:	Inorganica Chimica Acta. 333:93-99
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(02)00771-5
Popis:	Platinum(II) complexes with 1,2,4-triazolo[1,5-a]pyrimidines of general formula trans-[PtCl2(dmso)(L)], where L=1,2,4-triazolo[1,5-a]pyrimidine (tp), 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp), 5,7-diphenyl-1,2,4-triazolo[1,5-a]pyrimidine (dptp), 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine (dbtp) have been prepared by direct reaction between cis-[PtCl2(dmso)2] and respective 1,2,4-triazolo[1,5-a]pyrimidine in molar ratio M:L=1:1. All new platinum(II) compounds were characterized by 1H, 13C, 15N, 195Pt NMR and IR. Significant 15N NMR upfield shifts (75–87 ppm) were observed for N(3) atom indicating this nitrogen atom as a coordination site. Crystal structure of trans-[PtCl2(dmso)(dmtp)] (2) has been determinated. The molecular structure indicates that Pt(II) ion has the square-planar geometry with N(3) bonded dmtp, S-bonded dimethylsulfoxide and two trans chloride anions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::361291067fc3fc1d4c63522819c738f5 https://doi.org/10.1016/s0020-1693(02)00771-5 Zobrazit plný text záznamu Full Text from ScienceDirect