Synthesis, crystal structures, and thermal properties of Co(II), Ni(II), Cd(II), and Mn(II) coordination polymers based on 5-hydroxyiso phthalic acid and 1,1′-(1,4-butanediyl) bis (imidazole)
| Autor: | Ye Yang, Xiao-Yu Ren, Le Guo, Wei Dong, Yan-Peng Gao, Fei Chang, Min Jia |
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| Rok vydání: | 2016 |
| Předmět: |
Thermogravimetric analysis
Hydrogen bond Coordination polymer Inorganic chemistry Supramolecular chemistry Infrared spectroscopy 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Phthalic acid chemistry.chemical_compound Crystallography chemistry Imidazole Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Inorganic and Nano-Metal Chemistry. 47:41-49 |
| ISSN: | 2470-1564 2470-1556 |
| Popis: | Four coordination polymers, [Co(5-HO-bdc) (bbi)]n (1) and [M(5-HO-bdc)(bbi)]n {M = Ni(II) (2), Cd(II) (3), Mn(II)(4)} [5-OH-bdcH2 = 5-hydroxyisophthalic acid and bbi = 1,1′-(1,4-butanediyl)bis(imidazole)], have been synthesized under hydrothermal/solvothermal condition and structurally characterized by X-ray single-crystal and infrared spectra as well as elemental and thermogravimetric analyses. As a result, compound 1 exhibits multilayer weaving 3D geometrical structure, which is formed by multiple interpenetrated 2D (4,4)-connected networks with (44·62). Compounds 2–4 have formed isomorphous crystals and feature a 2D (4,4)-connected layer network in which the layers are connected to form a 3D supramolecular structure by hydrogen bonds. Both frameworks of 1 and 2 are stable below 400°C. |
| Databáze: | OpenAIRE |
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