Identification of the products of solvolysis of N-benzylpyridinium cations in the absence of nucleophiles

Autor:	Alan R. Katritzky, Roy W. King, Jen-luan Chen, Franciszek Saczewski, Charles M. Marson
Rok vydání:	1986
Předmět:	Nitrobenzene Solvent chemistry.chemical_compound chemistry Nucleophile Chlorobenzene Pyridine Thermal decomposition Leaving group Organic chemistry Solvolysis Medicinal chemistry
Zdroj:	Journal of the Chemical Society, Perkin Transactions 2. :1331
ISSN:	1364-5471 0300-9580
DOI:	10.1039/p29860001331
Popis:	Mono-, tri-, and penta-cyclic N-benzylpyridinium tetrafluoroborates undergo thermolysis in chlorobenzene as solvent to give products of benzylation both of the solvent and of the pyridine leaving group. Thermolysis alone, and in nitrobenzene as solvent, yielded mainly products of benzylation of the leaving group. The results support the previously postulated mechanism of unimolecular solvolysis of compounds of these types in non-polar solvents.
Databáze:	OpenAIRE
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