Trichlorooxo(triphenylphosphine)(triphenylphosphine oxide)rhenium(V)

Autor:	J. C. Bryan, Jeffrey B. Arterburn, Marc C. Perry
Rok vydání:	1998
Předmět:	chemistry.chemical_compound chemistry Stereochemistry chemistry.chemical_element Molecule Sulfoxide General Medicine Crystal structure Rhenium Triphenylphosphine Medicinal chemistry General Biochemistry Genetics and Molecular Biology Triphenylphosphine oxide
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 54:1607-1608
ISSN:	0108-2701
DOI:	10.1107/s010827019800818x
Popis:	The title complex, [ReCl 3 O(C 18 H 15 OP)(C 18 H 15 P)], is produced in a reaction between [Re(O)Cl 3 (PPh 3 ) 2 ] and ethyl 2-hydroxymethyl sulfoxide. The structure is compared to that of [Re(O)Cl 3 (PPhEt 2 )(OPPhEt 2 )] The Re-Cl distances are shorter [2.361 (2)-2.384 (2) A] and the Re-P distance is longer [2.506 (2) A] in the title complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::35a62e223bd76c2edb4b46439a25f995 https://doi.org/10.1107/s010827019800818x Zobrazit plný text záznamu Plný text