Déplacements Homolytiques Intramoléculaires : 15 - Additions Radicalaires A des Peroxydes β-Éthyléniques

Autor:	F. Rakotomanana, M. Agorrody, Evelyne Montaudon, Bernard Maillard
Rok vydání:	2010
Předmět:	Steric effects chemistry.chemical_compound chemistry Cyclohexane Organic chemistry General Chemistry Acetonitrile Decomposition Medicinal chemistry Peroxide Tetrahydrofuran Dichloromethane
Zdroj:	Bulletin des Sociétés Chimiques Belges. 96:769-774
ISSN:	0037-9646
DOI:	10.1002/bscb.19870961007
Popis:	Free radical additions of cyclohexane, tetrahydrofuran, methyl propanoate, acetonitrile, dichloromethane to allyl t-butyl peroxide, t-butyl 2-methyl prop-2-enyl peroxide, t-butyl 2,2-dimethyl prop-2-enyl peroxide and t-butyl 3-methyl but-2-enyl peroxide have been studied. Every step of the induced decomposition has been analyzed in terms of steric and polar effects, but no one itself could explain the observed results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::359c13fc50877193baf8f1ddfecd8b1e https://doi.org/10.1002/bscb.19870961007 Zobrazit plný text záznamu