Vapor−Liquid Equilibria at 413.65 K and Excess Enthalpies at 323.15, 363.15, and 413.15 K for Mixtures of Benzene, Toluene, Phenol, and Benzaldehyde

Autor:	Uwe Limbeck, and Simon H. Niemann, Bernd Nienhaus, Rainer Bölts, André B. de Haan, Jürgen Gmehling
Rok vydání:	1998
Předmět:	General Chemical Engineering Thermodynamics General Chemistry Toluene Toluene oxidation Group contribution method law.invention chemistry.chemical_compound chemistry law Azeotrope Non-random two-liquid model Organic chemistry Benzene Distillation UNIFAC
Zdroj:	Journal of Chemical & Engineering Data. 43:941-948
ISSN:	1520-5134 0021-9568
DOI:	10.1021/je980116z
Popis:	Isothermal P, x data at 413.65 K, excess enthalpies at 323.15, 363.15, and 413.15 K, and azeotropic data are presented for binary systems containing benzaldehyde, benzene, toluene, and phenol. Reliable information about the real behavior of systems including these components is very important for various chemical processes, e.g., for the production of phenol by toluene oxidation. Furthermore, these data will be used for the revision, extension, and further development of the group contribution method modified UNIFAC (Dortmund). The vapor−liquid equilibrium (VLE) data of four systems were measured using a static apparatus. In the case of the system benzaldehyde + phenol, azeotropic data were determined by distillation. For all systems, the corresponding experimental excess enthalpy (HE) data were determined with the help of an isothermal flow calorimeter. For the simultaneous description of VLE and HE data, the NRTL model was used.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::358392f92e284308d30a1c3c070e1016 https://doi.org/10.1021/je980116z Zobrazit plný text záznamu