Synthesis and NLO Properties of Calix[4]Arene Derivatives

Autor: Ming Feng Fang, Guo Yuan Lu
Rok vydání: 2011
Předmět:
Zdroj: Advanced Materials Research. :452-455
ISSN: 1662-8985
Popis: A novel calix[4]arene chromophore 1 was synthesized by introduction of two D-π-A units (4-nitrophenyl)azophenyloxy groups) on the lower rim of calix[4]arene. The measurement results of hyper-Rayleigh scattering (HRS) and UV-vis spectra show that the static first molecular hyperpolarizability of the chromophore 1 is more than two times that of the corresponding mono-D-π-A unit reference compound 4-(4-nitrophenylazo)phenol 2, without causing red-shift of absorption band.
Databáze: OpenAIRE