Molecular mobility in polyethylene after plastic flow under pressure

Autor: O.N. Saprygin, I. I. Barashkova, V.M. Litvinov, N.S. Yenikolopyan, V.A. Zhorin
Rok vydání: 1989
Předmět:
Zdroj: Polymer Science U.S.S.R.. 31:1437-1443
ISSN: 0032-3950
DOI: 10.1016/0032-3950(89)90178-0
Popis: A reduction in the translational diffusion of radicals occurs in HDPE as a result of plastic flow under pressure (2 GPa), and is due to a decrease in molecular mobility in the HDPE amorphous phase and to rearrangement of the crystalline phase. The impulse NMR data show that ordered regions are formed in amorphous phase of the polymer.
Databáze: OpenAIRE