Effect of Medium on the Electronic Spectra of 2-Nitroaniline Derivatives
| Autor: | Jan Jílek, Vojtěch Bekárek, Antonín Haviger |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
Physics::Biological Physics
Quantitative Biology::Biomolecules Series (mathematics) Chemistry Relative permittivity General Chemistry Spectral line Condensed Matter::Soft Condensed Matter Solvent Computational chemistry Absorption band Physical chemistry Wavenumber Physics::Chemical Physics Solvent effects Refractive index |
| Zdroj: | Collection of Czechoslovak Chemical Communications. 61:155-159 |
| ISSN: | 1212-6950 0010-0765 |
| Popis: | The wavenumbers of the long-wavelength absorption band were measured for nine 4-substituted and 5-substituted derivatives of 2-nitroaniline in the gaseous state and in 13 solvents where only nonspecific solvent-solute interactions can be expected. For the series involving all the solvents used, the solvent effects can be well expressed by an one-parameter equation involving the product of the Born functions of the relative permittivity and of the refractive index of the solvent. For the series involving the nonpolar solvents and the gaseous state only, this equation reduces to an one-parameter equation involving the refractive index Born function squared. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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