Photoorganocatalytic Atom Transfer Radical Addition of Bromoacetonitrile to Aliphatic Olefins

Autor:	Mary K. Apostolopoulou, Christoforos G. Kokotos, Anna Dimitra D. Gerogiannopoulou, Errika Voutyritsa, Nikolaos F. Nikitas
Rok vydání:	2018
Předmět:	Bromoacetonitrile chemistry.chemical_compound chemistry 010405 organic chemistry Benzoin Atom-transfer radical-polymerization Organic Chemistry Photocatalysis 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences
Zdroj:	Synthesis. 50:3395-3401
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0037-1610138
Popis:	A green and cheap protocol for the photocatalytic atom transfer radical addition (ATRA) of bromoacetonitrile to aliphatic alkenes is presented. The use of benzoin methyl ehter as the photocatalyst and irradiation using a household lightbulb leads to a highly useful synthetic method for the conversion of a wide range of substituted aliphatic olefins into the corresponding bromonitriles.
Databáze:	OpenAIRE
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