Fluoro-ketones VIII. Synthesis of some fluoroquinoxaline compounds from fluoroketones
| Autor: | Christ Tamborski, Loomis S. Chen, Kent J. Eisentraut, M.T. Ryan, Costandy S. Saba |
|---|---|
| Rok vydání: | 1986 |
| Předmět: |
Diketone
chemistry.chemical_classification Reaction mechanism Bicyclic molecule Chemistry Organic Chemistry Nuclear magnetic resonance spectroscopy Biochemistry Haloketone Inorganic Chemistry chemistry.chemical_compound Quinoxaline Mass spectrum Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry Aliphatic compound |
| Zdroj: | Journal of Fluorine Chemistry. 30:385-398 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/s0022-1139(00)85094-0 |
| Popis: | The reaction between a perfluoroalkylether α,β-diketone or perfluoroalkyletherketoester and o-phenylenediamine yielding quinoxaline compounds was studied in detail. The various intermediate compounds leading to the formation of the quinoxalines were examined by NMR, MS, GC/MS and IR. 2,3-Perfluoroalkylether substituted quinoxaline is the major product of the reaction. In addition however, the formation of a minor product 3-perfluoro-alkylether-2(1H)-quinoxalinone, indicates an alternate reaction path. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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