Electrochemical Methoxylation of Arylacetates

Autor:	Shohei Suzuki, Ken-ichi Kawai, Shoichi Nakajima, Koohei Nozawa, Miyako Shimamura, Mitsuko Kato
Rok vydání:	1992
Předmět:	Reaction mechanism Phenylacetates chemistry.chemical_element General Chemistry General Medicine Methoxide Electrochemistry Iodine Medicinal chemistry chemistry.chemical_compound chemistry Drug Discovery Succinates Organic chemistry Methanol Methylene
Zdroj:	Chemical and Pharmaceutical Bulletin. 40:1037-1038
ISSN:	1347-5223 0009-2363
DOI:	10.1248/cpb.40.1037
Popis:	Electrochemical methoxylation at the active methylene group of phenylacetates and 1-naphthaleneacetate was conducted successfully at room temperature, in methanol containing potassium iodide as an electron carrier and solium methoxide as a bade and a methoxylating agent. Along with the mono-methoxylated products, dimethoxy, hydroxy, and oxo derivatives as well as the dimers (succinates) were produced as by-products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::35076405669ad7b04e55d6dce8e1a536 https://doi.org/10.1248/cpb.40.1037 Zobrazit plný text záznamu