Structural and thermodynamic characteristics of dilute solutions of alcohols in aprotic solvents

Autor:	E. I. Grushova, A. I. Yusevich
Rok vydání:	2007
Předmět:	Steric effects chemistry.chemical_compound Ethanol chemistry Viscous flow Inorganic chemistry Physical and Theoretical Chemistry
Zdroj:	Russian Journal of Physical Chemistry A. 81:1976-1979
ISSN:	1531-863X 0036-0244
Popis:	The enthalpies of H-bonds in ethanol and isopropanol complexes with aprotic solvents, extractants of aromatic hydrocarbons, were determined. The thermodynamic functions of viscous flow activation and the mean degrees of association in dilute solutions of the alcohols in N-methylpyrrolidone, dimethylsulfoxide, and tetramethylenesulfone were obtained. The roles played by the energy and steric effects in the solution of alcohols in the solvents were estimated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::34fc59d100ed58827c2af99bc5ccdd11 https://doi.org/10.1134/s0036024407120126 Zobrazit plný text záznamu Full text from SpringerLink