ChemInform Abstract: Cross-Coupling of Mesylated Phenol Derivatives with Potassium Cyclopropyltrifluoroborate

Autor:	Floriane Beaumard, Terren K. Niethamer, Gary A. Molander
Rok vydání:	2011
Předmět:	chemistry.chemical_compound chemistry Aryl Yield (chemistry) Potassium Electrophile chemistry.chemical_element Phenol General Medicine Medicinal chemistry Palladium catalyst
Zdroj:	ChemInform. 43
ISSN:	0931-7597
DOI:	10.1002/chin.201203044
Popis:	C–O activation of mesylates by a palladium catalyst and subsequent cross-coupling with potassium cyclopropyltrifluoroborate have been achieved with high yield. Both electron-enriched and electron-deficient aryl mesylates are suitable electrophilic partners for the Suzuki–Miyaura reaction. The scope was successfully extended to heteroaryl mesylates with yields up to 94%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::34c981777f9a5f5fe9be42a00dd52f74 https://doi.org/10.1002/chin.201203044 Zobrazit plný text záznamu Plný text