An in situ ESR study of the intercalation mechanism: HOPG/fluorine and HOPG/HNO3
| Autor: | I. Palchan, Henry Selig, Dan Davidov, V. Zevin, G. Polatsek |
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| Rok vydání: | 1985 |
| Předmět: |
In situ
Materials science Mechanical Engineering Diffusion Intercalation (chemistry) Metals and Alloys chemistry.chemical_element Nanotechnology Condensed Matter Physics Electronic Optical and Magnetic Materials Crystallography Highly oriented pyrolytic graphite chemistry Mechanics of Materials Yield (chemistry) Materials Chemistry Fluorine skin and connective tissue diseases Layer (electronics) |
| Zdroj: | Synthetic Metals. 12:413-418 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/0379-6779(85)90144-4 |
| Popis: | An in situ ESR study of Highly Oriented Pyrolytic Graphite (HOPG) indicates dramatic changes in the ESR lineshape (A/B ratio) and intensity upon exposure to fluorine or HNO3. The results can be interpreted by the formation of a macroscopic intercalation layer and the advance of the boundary separating this layer from the as yet unintercalated HOPG. The measurements yield the diffusion coefficients during the intercalation process. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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